AustralieFrV1, Main, Exploration, bibRecord, 004987

Pressure‐Induced Polyamorphism and Formation of ‘Aragonitic’ Amorphous Calcium Carbonate

Identifieur interne : 004987 ( Main/Exploration ); précédent : 004986; suivant : 004988

Pressure‐Induced Polyamorphism and Formation of ‘Aragonitic’ Amorphous Calcium Carbonate

Auteurs : Alejandro Fernandez-Martinez [France, États-Unis] ; Bora Kalkan [États-Unis] ; Simon M. Clark [États-Unis, Australie] ; Glenn A. Waychunas [États-Unis]

Source :

Angewandte Chemie International Edition [ 1433-7851 ] ; 2013-08-05.

RBID : ISTEX:C67DCD7065C6CFBECD8DCCFC44719AD3A0007D51

English descriptors

Abstract

Pressed for time: Amorphous calcium carbonate (ACC) undergoes a reversible amorphous–amorphous phase transition at 10 GPa, adopting an aragonite‐like local order. This result suggests a mechanism by which Mg2+—a cation with smaller ionic radius than Ca2+—modifies the local order of ACC to an aragonite‐like order by helping to decrease the molar volume of the amorphous phase.

Url:

https://api.istex.fr/document/C67DCD7065C6CFBECD8DCCFC44719AD3A0007D51/fulltext/pdf

DOI: 10.1002/anie.201302974

Affiliations:

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Le document en format XML

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<front><div type="abstract">Pressed for time: Amorphous calcium carbonate (ACC) undergoes a reversible amorphous–amorphous phase transition at 10 GPa, adopting an aragonite‐like local order. This result suggests a mechanism by which Mg2+—a cation with smaller ionic radius than Ca2+—modifies the local order of ACC to an aragonite‐like order by helping to decrease the molar volume of the amorphous phase.</div>
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Pressure‐Induced Polyamorphism and Formation of ‘Aragonitic’ Amorphous Calcium Carbonate

Pressure‐Induced Polyamorphism and Formation of ‘Aragonitic’ Amorphous Calcium Carbonate

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri